Abstract
Research was conducted to illustrate relevant questions about H2S removal from yellow phosphorus off-gas through catalytic-oxidizing method. Following results have been found out. Firstly, Molecule sieve ZMS-5A, activated carbon ZP-1, ZP-2, ZP-3 and ZP-4 were used as carrier to identify their performances on H2S removal, among which ZP-4 was the optimum one. Secondly, among 3 different impregnants tested in experiments, Na2CO3 was the ideal one to be used as active ingredients of catalyst. And 7% was the suitable concentration of Na2CO3 according to experiments. Finally, catalyst made of carrier ZP-4 impregnated with 7% Na2CO3 was assessed comprehensively to investigate its performance on impurity removal of PH3, H2S, SO2, COS, and CS2. After purification total impurity content in yellow phosphorus off-gas was less than 10g/Nm3, which means purified gas can be used as material as mono-carbon chemical industry.
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