Abstract

In this paper, a portable electronic nose, that was independently developed, was employed to detect and classify a fish meal of different qualities. SPME-GC-MS (solid phase microextraction gas chromatography mass spectrometry) analysis of fish meal was presented. Due to the large amount of data of the original features detected by the electronic nose, a reasonable selection of the original features was necessary before processing, so as to reduce the dimension. The integral value, wavelet energy value, maximum gradient value, average differential value, relation steady-state response average value and variance value were selected as six different characteristic parameters, to study fish meal samples with different storage time grades. Principal Component Analysis (PCA) and Linear Discriminant Analysis (LDA), and five recognition modes, which included the multilayer perceptron neural network classification method, random forest classification method, k nearest neighbor algorithm, support vector machine algorithm, and Bayesian classification method, were employed for the classification. The result showed that the RF classification method had the highest accuracy rate for the classification algorithm. The highest accuracy rate for distinguishing fish meal samples with different qualities was achieved using the integral value, stable value, and average differential value. The lowest accuracy rate for distinguishing fish meal samples with different qualities was achieved using the maximum gradient value. This finding shows that the electronic nose can identify fish meal samples with different storage times.

Highlights

  • Fish meal is a high protein feed made from one or more kinds of fish, which is deoiled, dehydrated, and crushed

  • The energy value, maximum gradient value, and variance value were employed as characteristic parameters to distinguish fish meal samples with different storage times. Based on these characteristic values, this study investigated fish meal samples of different qualities, determined appropriate characteristic values, and achieved better distinguishing results for fish meals of different qualities by some classification algorithms, such as Principal Component Analysis (PCA), Linear Discriminant Analysis (LDA)

  • The 6 fish meal samples were classified according to the acid value, which was made as a freshness evaluation index

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Summary

Introduction

Fish meal is a high protein feed made from one or more kinds of fish, which is deoiled, dehydrated, and crushed. With an increase in the aquaculture scale in China in recent years, the demand for aquatic feed is rapidly increasing, and the demand for fish meal shows sustained growth. Fish meal is a highly valued source of feed proteins because it is digested and has excellent essential amino acids, other essential nutrients, and DHA. Fish meal is an excellent source of vitamins (such as riboflavin, nicotinic acid, vitamin A, and vitamin D) and minerals (such as calcium, phosphorus, iron, zinc, selenium, and iodine) [1] and is the main animal-derived feed raw material in the feed industry. The quality of fish meal directly affects the quality of feed products [2]. During the storage process of fish meal, the quality and nutritional components of fish meal vary by different degrees due to weather changes, temperature, humidity, mold, and other microorganisms, which affect the Sensors 2019, 19, 2146; doi:10.3390/s19092146 www.mdpi.com/journal/sensors

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