Abstract

Abstract : Gem-diperchlorates were obtained by the reaction of ketones with anhydrous perchloric acid in halogenated solvents. Cyclohexene was reduced to cyclohexane by perchloric acid in chloroform. Isopropyl chlorofluorocarbamate and bromofluorocarbamate added to olefins and acted as halogenating agents toward hydrcarbons by free radical chain mechanisms involving fluoraminocarboalkoxy free radicals. Isopropyl fluorocarbamate and mercuric oxide gave bis(carboisopropoxyfluoramino)mercury. The latter was found to add to olefins. The following phases of earlier research were completed and the work was assembled in the form of manuscripts: (1) Direct fluorination of ureas, (2) Direct fluorination of amides, and (3) Synthesis of alpha,alpha-dinitro-N'-fluorodiimide N-oxides. (Author)

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