Research data supporting "Ureasil Organic-Inorganic Hybrids as Photoactive Waveguides for Conjugated Polyelectrolyte Luminescent Solar Concentrators"

Abstract

The folder “Figure 2” contains the data for the steady-state optical properties of PBS-PFP-PDI in solution (water:1,4-dioxane (1:1(v/v)) and selected doped and undoped di- and tri-ureasil LSCs in the solid-state: (a) Absorption, excitation and emission spectra of PBS-PFP-PDI (10-6 mol dm-3, λex = 360 nm, λem = 660 nm). Emission spectra of (b) DU-CPE-0, (c) DU-CPE-08 and (d) TU-CPE-08 at different excitation wavelengths and excitation spectra of (e) DU-CPE-08 and (f) TU-CPE-08 at different emission wavelengths. The folder “Figure 3” contains the data for FTIR spectra and the corresponding Gaussian curve-fits of the amide I region of (a) DU-CPE-0 and (b) TU-CPE-0. The folder “Figure 4” contains the data for emission decay curves, the corresponding fits and the instrument response function (IRF) for PBS-PFP-PDI in solution (water/1,4-dioxane (1:1 (v/v)), DU-CPE-x and TU-CPE-x at selected excitation and emission wavelengths: (a) DU-CPE-0 and TU-CPE-0 (λex = 370 nm, λem = 420 and 500 nm). (b) PBS-PFP-PDI and DU-CPE-x (λex = 370 nm, λem = 420 nm) and (c) PBS-PFP-PDI and TU-CPE-x (λex = 370 nm, λem = 420 nm). As well as the weighted residuals for each fit. The folder “Figure 5” contains the data for (a) optical power spectra of DU-CPE-0, DU-CPE-08, TU-CPE-0, TU-CPE-08 with a dark absorbing background and (e) optical power spectra of DU-LR305 and DU-PBS-LR305 with a dark absorbing background. The folder “Figure S1” contains the data for the excitation spectra of (a) DU-CPE-0 and (c) TU-CPE-0 at different emission wavelengths and the emission spectra of (b) TU-CPE-0 at different excitation wavelengths. The folder “Figure S2” contains the data for the emission spectra of (a) DU-CPE-02, (b) DU-CPE-04, (c) TU-CPE-02 and (d) TU-CPE-04 at different excitation wavelengths. The folder “Figure S3” contains the data for the excitation spectra of (a) DU-CPE-02, (b) DU-CPE-04, (c) TU-CPE-02 and (d) TU-CPE-04 at different emission wavelengths. The folder “Figure S4” contains data for the FTIR spectra and the corresponding Gaussian curve0fits of the Amide I region of (a) DU-CPE-02, (b) DU-CPE-04, (c) DU-CPE-08, (d) TU-CPE-02, (e) TU-CPE-04 and (f) TU-CPE-08 The folder “Figure S5” contains data for the emission decay curve and the corresponding fir for TU-CPE-08 (λex = 466 nm and λem = 600 nm). The fitted decay times, weighted residuals and the instrument response function are also shown. The folder “Figure S6” contains data for the emission decay curves and the corresponding fits for a (a) DU-CPE-02 (b) DU-CPE-04 and (c) DU-CPE-08 upon excitation at 370 nm (λem = 500 nm). The fitted decay times, weighted residuals and the instrument response function are also shown. The folder “Figure S7” contains data for the emission decay curves and the corresponding fits for (a) TU-CPE-02, (b) TU-CPE-04 and (c) TU-CPE-08 upon excitation at 370 nm (λem = 500 nm). The fitted decay times, weighted residuals and the instrument response function are also shown. The folder “Figure S8” contains the data for the optical pwer spectrum of the solar simulator (AM1.5G).