Abstract
The production of Cl atoms in the laser flash photolysis of ClOOCl at 308nm has been investigated by time-resolved atomic resonance fluorescence at 235K. A value of ϕ=1.03±0.12 has been obtained for the primary quantum yield based on an absorption cross section ratio σ245/σ308=22 for ClOOCl at 245 and 308nm.
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