Abstract
<strong class="journal-contentHeaderColor">Abstract.</strong> The electrical conductivity of gabbroic melt with four different water contents (i.e. 0, 2.59 wt%, 5.92 wt% and 8.32 wt%) was measured at temperatures of 873–1373 K and pressures of 1.0–3.0 GPa using YJ–3000t multiâanvil high−pressure apparatus and Solartronâ1260 impedance spectroscopy analyzer. At a fixed water content of 2.59 wt%, the electrical conductivity of the sample slightly decreased with increasing pressure at the temperature range of 873â1373 K, and its corresponding activation energy and activation volume were determined as 0.87 ± 0.04 eV and â1.98 ± 0.02 cm<sup>3</sup> mole<sup>–1</sup>, respectively. Under the certain conditions of 873â1373 K and 1.0 GPa, the electrical conductivity of the gabbroic melts tends to gradually increase as the rise of water content from 0 to 8.32 wt%, and the activation enthalpy decreases from 0.93 eV to 0.63 eV, accordingly. Furthermore, the functional relation models for the electrical conductivity of gabbroic melts with the variations of temperature, pressure and water content were constructed at highâtemperature and highâpressure conditions, respectively. In addition, the dependence relation of the electrical conductivity of melts with the degree of depolymerization was explored under conditions of four different water contents, 1373 K and 1.0 GPa, and three previously available reported results on those of representative calcâalkaline igneous rock melts (i.e. dacitic melt, basaltic melt and andesitic melt) were detailedly compared. In comprehensive combination with our presently acquired electrical conductivity data of gabbroic melt with four different water contents and the available data of polycrystalline olivine, the electrical conductivity of gabbroic meltâolivine system on the variation of volume percentage of anhydrous and hydrous melts was successfully constructed by virtue of the typical Hashin–Shtrikman upper bound model. In light of the electrical conductivity of gabbroic meltâolivine system with the previous MT results, we find that the anhydrous and hydrous gabbroic melts can be employed to reasonably interpret the high conductivity anomalies in the Mohns ridge of the Arctic Ocean.
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