Abstract

The associative replica Ornstein-Zernike equations, supplemented by the associative hypernetted chain approximation are used to describe the Smith-Nezbeda model for an associating fluid adsorbed in a disordered hard sphere matrix. These equations have been developed by combining the replica Ornstein-Zernike equations with the Wertheim theory of association in fluids. The pair distribution functions and fraction of unbonded species are calculated. Also investigated is the influence of the association on the equation of state and the chemical potential of the absorbed fluid.

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