Renovated filter filled with poly-3-hydroxybutyrateco-hydroxyvalerate and granular activated carbon for simultaneous removal of nitrate and PPCPs from the secondary effluent

Abstract

Reclaimed water is in huge demand in water-deficient cities. However, nitrogen, pharmaceuticals and personal care products (PPCPs) are frequent contaminants in reclaimed water that are probable to bring environmental risks. To develop a technology for safe reclaimed water production, in this study, a renovated filter that integrates solid-phase denitrification (SPD) with biodegradable polymer poly-3-hydroxybutyrate-co-hydroxyvalerate (PHBV) and granular activated carbon (GAC) adsorption (SPD-GAC filter) was proposed and applied to remove nitrogen and target PPCPs (metoprolol and diclofenac) simultaneously. The influences of different ratio of the filled PHBV and GAC, and the hydraulic retention time (HRT) on the removal performances were investigated. The results showed that the filter with PHBV/GAC = 1 (25 cm PHBV/25 cm GAC) simultaneously achieved an average NO3−-N removal efficiency of about 95% with no accumulation of ammonia and nitrite, and an average removal efficiency of PPCPs of about 80%. Compared with PHBV-based SPD system, the integrated SPD-GAC filter significantly improved the control of carbon release and the PPCP removals. SPD-GAC filter also exhibited a strong tolerance for the variation of influent NO3−-N loading rate, achieving a highest denitrification rate of 0.76–0.82 g N·(L·d)−1. The integrated SPD-GAC filter proves to be a promising technology for the simultaneous removal of nitrogen and PPCPs from the secondary effluent.