Removal performance and mechanisms of Pb(II) and Sb(V) from water by iron-doped phosphogypsum: single and coexisting systems.

Abstract

The serious environmental risks caused by Pb(II) and Sb(V) co-contamination increase the need for their efficient and simultaneous removal. In this study, the remediation feasibility by Fe-doped phosphogypsum (FPG) was elucidated for single systems with Pb or Sb pollutant and coexisting systems with both from water. As for single systems, Fe doping effectively enhanced the Pb(II) removal performance by phosphogypsum (PG) at low Pb(II) concentrations of below 100mg/L via the combination of precipitation and complexation. The optimal removal rate of Sb(V) by FPG increased by 2.08-3.31 times as compared to that of by PG (10-120mg/L), mainly due to the strong affinity of iron hydroxyl (≡Fe-O-H) towards Sb(V). Compared with the single systems, the coexistence greatly enhanced the Pb(II) and Sb(V) removal performance by FPG, and the interaction behavior between Pb(II) and Sb(V) on the FPG was concentration dependent. Briefly, the sorption of FPG controlled the elimination of low coexisting concentrations of Pb(II) and Sb(V), whereas the co-precipitation process between Pb(II) and Sb(V) predominated with high ions concentration. The significant synergistic effects were found during the removal of Pb(II) and Sb(V) on FPG in the coexisting system, which mainly attributed to precipitation, bridging complexation and electrostatic attraction. Considering the advantages such as facile preparation, low cost and high removal capacity, FPG is a promising material to uptake Pb(II) and/or Sb(V) from contaminated water.