Removal of undissolved substances in the dissolution-based recycling of polystyrene waste by applying filtration and centrifugation

Abstract

Polystyrene (PS) is a versatile polymer typically used in applications such as yogurt cups, packaging trays, disk cases and toys. To increase recycling rates of PS, dissolution recycling is being investigated, which involves the liquefication of the polymer in a suitable solvent, allowing deep cleaning of the polymer from impurities. Quite specific to PS is that polystyrene waste contains both general-purpose polystyrene and high-impact polystyrene (HIPS), which is composed of free PS and polystyrene-grafted polybutadiene particles. In this work the potential of filtration and centrifugation is analyzed with the aim of cleaning the polymer from both, insoluble PB-PS particles and pigments (TiO2, Cr/Sb/Ti oxide and carbon black). The dead-end lab scale filtration were performed at room temperature and at pressures between 1.5 and 30 bar. The pigments were successfully removed, yet, filtration of HIPS solutions results in low fluxes due to extreme membrane fouling caused by the PB-PS particles, which was confirmed by the application of pore-blockage filtration models. Alternatively, centrifugation at 14,052 G-force has shown to be a promising alternative to separate the particles from HIPS, resulting in 100% turbidity reduction. Equally, the separation of pigments was successful, highlighting that TiO2 and Cr/Sb/Ti oxide have shorter sedimentation times compared to carbon black. Finally, the two separation processes are tested on a PS rigid packaging waste sample coming from a sorting line and the results show that centrifugation allows a high turbidity reduction and that a two-step separation process starting with centrifugation for PB-PS particles removal can facilitate further downstream cleaning.