Removal of Terephthalic Acid from Waste Water Using Diatomite Adsorbent

Abstract

Adsorption-catalytic oxidation of terephthalic acid (TA) from waster water using modified diatomite adsorbent was studied in this paper. Two diatomites were chosen for adsorbents and TA was used as a model compound. The process consists of physic adsorption of TA and catalytic oxidation of TA. The concentration of TA was determined by UV spectrometry. The results indicate that adsorption capacity of diatomite increased with the decrease of pH value of waster water. The equilibrium adsorbed amount of modified diatomite increased with the increase of metal content in the initial metal content range from 0 to 5% for both of Ni, Fe and Cu modified diatomite, and then the equilibrium adsorbed amount decreased after 5% metal content for Ni modified diatomite and in general kept constant for Fe and Cu modified diatomite. The maximum amount of TA adsorbed at the equilibrium stage was 4.40mg/g for Ni-5/RD. The adsorption capacity of raw and modified diatomite decreased obviously with the increase of cycle number in the initial first-fourth of cycle and then decreased very slowly in the 5th-10th of cycle. The Qe of Ni-5/RD, Fe-5/RD, Cu-5/RD and RD in the 10th cycle were 3.12, 2.44, 1.87 and 0.12mg/g, respectively. The result indicated that the modified could be repeatedly used and maintained the adsorption/regeneration performance stably through many batches of operation.