Removal of reactive orange 16 and reactive green 19 using Cyphos IL101-impregnated Amberlite XAD7HP resin in batch and recirculating stirrer vessel.

Abstract

Reactive dyes are highly soluble in water, and carcinogenic. Therefore, it is essential to remove these dyes from their aqueous solutions. This study focused on the simultaneous removal of reactive orange 16 (RO) and reactive green 19 (RG) dyes from their binary dye solution using Cyphos IL101-impregnated Amberlite XAD7HP resin (ILX7) in batch and recirculating stirrer vessel (RSV). In the batch study, the experimental operating conditions were designed by using central composite design of response surface methodology. Influence of important input variables (RO dye concentration, RG dye concentration, pH, and resin dosage) on the dye adsorption was studied and their values were optimized. At the optimum values of input variables, equilibrium, kinetic, and thermodynamic studies were performed for the binary dye mixture. The equilibrium and kinetic adsorption data were best fitted with extended-Freundlich and pseudo-second-order models, respectively. Now to intensify the process, continuous studies were performed in a RSV at optimum conditions and at different flow rates and stirring speeds. The impregnated resin was regenerated by using 80% v/v ethanol and successfully reused up to 3 cycles with slight decrease in the adsorption capacity.