Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite

Abstract

The natural zeolite tuff (clinoptilolite) from a Serbian deposit has been studied as adsorbent for Ni(II) ions from aqueous solutions. Its sorption capacity at 298 K varies from 1.9 mg Ni g −1 (for the initial solution concentration of 100 mg Ni dm −3) to 3.8 mg Ni g −1 (for C 0 = 600 mg Ni dm −3) and it increases 3 times at 338 K. The sorption is best described by the Sips isotherm model. The sorption kinetics follows the pseudo-second-order model, the activation energies being 7.44, 5.86, 6.62 and 6.63 kJ mol −1 for C 0 = 100, 200, 300 and 400 mg Ni dm −3, respectively. The sorption involves a film diffusion, an intra-particle diffusion, and a chemical cation-exchange between the Na + ions of clinoptilolite and the Ni 2+ ions. The sorption is endothermic (Δ H° being 37.9, 33.4, 30.0, 27.7 and 24.3 kJ mol −1 for C 0 = 100, 200, 300, 400 and 600 mg Ni dm −3, respectively) and spontaneous in the 298–338 K temperature range. Thermal treatment of the Ni(II)-loaded clinoptilolite results in the formation of spherical nano-NiO particles of approx. 5 nm in diameter which are randomly dispersed in the clinoptilolite lattice.