Removal of landfill leachate ultraviolet quenching substances by electricity induced humic acid precipitation and electrooxidation in a membrane electrochemical reactor

Abstract

Persistent UV quenching substances (UVQS) in landfill leachate can affect the effectiveness of UV disinfection in domestic wastewater treatment systems when leachate is being co-treated. As a result, effective onsite leachate pre-treatment will have to be implemented to reduce the UV quenching capability. Herein, a membrane electrochemical reactor (MER) was developed and investigated for treating UV quenching organics contained in landfill leachate. Compared to a control reactor that did not have a membrane separator, the MER achieved significantly higher removals of both dissolved organic carbon (61.5 ± 4.1%) and UV254nm absorbance (63.4 ± 8.4%). This enhanced performance was likely due to the combined effects of humic acid precipitation and augmented oxidation of organics. The MER was able to remove 89.1 ± 2.9% of total nitrogen from the leachate while recovering about 51% of the influent ammonia in the catholyte, in comparison to 38.1 ± 4.4% of total nitrogen removal by the control reactor. The MER consumed significantly less electrical energy with specific energy consumption of 70.62 kWh kg−1 DOC or 33.03 kWh kg−1 sCOD, compared to that of the control reactor (211.8 kWh kg−1 DOC or 55.02 kWh kg−1 sCOD). A current density of 20 mA cm−2 was considered optimal in terms of both UVQS removal and energy efficiency. Consideration should be given to the spacing of electrodes to minimize internal resistance and also to avoid trapping of the produced gas bubbles. These results collectively suggest that the MER is a promising onsite pretreatment approach for landfill leachate and further exploration of this technology should be encouraged.