Removal of inorganic toxic contaminants from wastewater using sustainable biomass: A review

Abstract

Lignocellulosic biomass is most abundant, ecofriendly and sustainable material on this green planet which has received great attention due to exhaustion of petroleum reserves and various environmental complications. Due to its abundance and sustainability, it has been opted in number of advanced applications i.e. synthesis of green chemicals, biofuels, paper, packaging, biocomposite and for discharge of toxic contaminants from wastewaters. Utilization of sustainable biomass for removal of toxic pollutants from wastewater is robust technique due to its low-cost and easy availability. In this review, we have summarized removal of inorganic pollutants by sustainable lignocellulosic biomass in their natural as well as in chemically functionalized form. Various techniques for modification of sustainable biomass have been discussed and it was found that modified biomass showed better biosorption ability as compared to natural biomass. We conclude that modified biomass biosorbents are useful for removal of toxic inorganic pollutants to deficient levels. Several modification strategies can improve the qualities of biosorbent, however grafting is the most successful among them, as demonstrated in this work. The numerous grafting methods using a free radical grafting process are also summarized in this review article. This review also gathers studies comparing sorption capabilities with and without modification using modified and unmodified biosorbents. Chemically modified cellulosic biomass is favoured over untreated biomass because it has a higher adsorption efficiency, which is favoured by a large number of reactive binding sites, improved ion-exchange characteristics, and more functional groups available after modification.