REMOVAL OF HEXAVALENT CHROMIUM FROM AQUEOUS MEDIA USING MEDITERRANEAN POSIDONIA OCEANICA BIOMASS: ADSORPTION STUDIES AND SALT COMPETITION INVESTIGATION

Abstract

The biosorption of hexavelent chromium from saline solutions by Posidonia oceanica, a marinebiomass, was studied as a function of pH, initial chromium (VI) and salt (NaCl) concentrations in batchsystem. The sorbent exhibited the maximal chromium (VI) uptake at pH 2 regardless of the presence ofincreasing salt concentration. Equilibrium uptake increased with chromium (VI) concentration up to 250 mg/l and decreased slightly in the presence of increasing salt concentrations of salt up to 50 g/l. The biomassadsorbed 14.48 mg of metal per gram of biomass at 100 mg/l initial chromium concentration in the absence ofsalt. When 50 g/l salt concentration was added to the solution, the value diminished to 11.49 mg/g under thesame conditions (i.e. a 20.6% decrease in the biosorption capacity). The equilibrium sorption data wereanalyzed using Freundlich, Langmuir and Redlich-Peterson models. The Langmuir equation was the mostsuitable adsorption model for describing the biosorption equilibrium data of chromium (VI) both in salt freeand loaded media. The pseudo-second-order type kinetic model depicted the biosorption kinetics accuratelyat all chromium concentrations in absence and presence of increasing concentrations of salt.