Removal of heavy metal ions with magnetic carbon prepared from corncob biomass

Abstract

Four novel magnetic-activated carbons (MACs) were prepared, characterized, and used as adsorbents to remove heavy metal ions from wastewater samples. The MACs prepared, are advanced adsorbents for the removal of Hg(II), Cr(III), Cd(II), and Pb(II). The nature of the acid, amount, composition of the MACs, and the remotion time were evaluated in aqueous solutions. The ions removal percentages obtained, under the best conditions, were 93% for Hg(II) and higher than 99% for Pb(II), Cr(III), and Cd(II) (100 mg L-1, initial concentration in solution), with 100 mg of the MAC-3 in HNO3 3 mM. The capacity of the best adsorbent, MAC-3, for removing heavy metals ions Hg(II), Cr(III), Cd(II), and Pb(II) was studied using Langmuir and Freundlich adsorption isotherms under the best condition. The maximum adsorption capacities of Hg(II), Cr(III), Cd(II), and Pb(II) were found to be 10.72, 11.51, 11.49 and 11.49 mg g−1, the values of constants of Freundlich models were 17.98, 26.83, 9.18, and 7.18 mg g−1 respectively. For Hg(II) and Pb(II) the correlation factor (R2) was better for Freundlich model, while Cr(III) and Cd(II) showed better R2 with Langmuir model. Finally, the treatment for the elimination of heavy metal ions was carried out, with wastewater samples of industrial and domestic origin, and used for crop irrigation. The samples were collected in Irrigation District 003, Hidalgo, Mexico. The MAC-3 removes heavy metal ions from the wastewater matrix above 99%.