Removal of Contaminants from Industrial Lean Amine Solvent Using Polyacrylamide Hydrogels Optimized by Response Surface Methodology

Abstract

Response surface methodology (RSM) based on a three-level, three-variable model was used to optimize the preparation parameters of a hydrogel consisting of acrylamide (AAM) as monomer, N, N'-methylenebisacrylamide as cross-linker and ammonium peroxodisulphate as initiator. Considering percentage removal of total metal ions (contaminants) as the treatment response, the effects of three variables, namely, wt% AAM, wt% cross-linker and temperature of polymerization were investigated. The polyacrylamide (PAAM) hydrogel was obtained as small beads and optimized using RSM. The hydrogel was used for the removal of total metal ions and total organic acid anions (known as heat-stable salts, HSSs) from industrial lean methyl diethanolamine solvents (MDEA, 50 wt% used by Gasco, Habshan, Abu Dhabi for natural gas sweetening). The presence of heavy-metal ions and HSS is responsible for many problems such as corrosion, foaming and fouling of the equipment. The PAAM hydrogel was characterized by determining its cross-li...