Removal of chromium(VI) and dye Alizarin Red S (ARS) using polymer-coated iron oxide (Fe3O4) magnetic nanoparticles by co-precipitation method

Abstract

The present research was conducted with an aim to develop such adsorbent system: polymer-coated magnetic nanoparticles which can remove heavy metal and dye from water of different concentration. Synthesis of magnetic iron oxide nanoparticles for contaminated water purification has been one of the outcomes of application of rapidly growing field of Nanotechnology in Environmental Science. In the present study, the efficiency of magnetic nanoparticles for removal of Cr(VI) and dye (alizarin) from water solutions of known concentrations were evaluated. The nanoparticles were prepared by co-precipitation method and characterized by X-ray photoelectron spectroscopy, transmission electron microscopy, and Fourier transform infrared spectroscopy. Polymer-coated magnetic iron oxide nanoparticles carrying functional groups on their surface were synthesized by different methods for permanent magnet-assisted removal of heavy metal (chromium) and dye (Alizarin Red S) from water. The characterization showed that synthesized nanoparticles were in the size range of 10–50 nm. The adsorption capacities of the Fe3O4 using polyMETAC-coated particles for dye (Alizarin Red S) removal were 80–96 % and chromium 62–91 %. The chromium concentration was determined after magnetic separation using atomic absorption spectrophotometer and dye concentration was estimated with UV–visible spectrophotometer. Nanoparticles of polymer coated showed the highest removal capacity from water for metal and dye. The developed adsorbents had higher capacity for removal of heavy metal ions and dye.