Removal of chromium (VI) from aqueous solutions using quaternized chitosan microspheres

Abstract

In this study, quaternized chitosan microspheres (QCMS) were prepared and its Cr (VI) removal potential was investigated. Batch experiments were conducted to examine kinetics, adsorption isotherm, pH effect, and thermodynamic parameters. Equilibrium was attained within 50min and maximum removal of 97.34% was achieved under the optimum conditions at pH5. Adsorption data for Cr (VI) uptake by the QCMS were analyzed according to Langmuir, Freundlich, and Temkin adsorption models. The maximum uptake of Cr (VI) was 39.1mg·g−1. Thermodynamic parameters for the adsorption system were determinated at 293K, 303K, 313K and 323K. (ΔH°=16.08kJ·mol−1;ΔG°=−5.84 to −8.08kJ·mol−1 and ΔS°=74.81J·K−1·mol−1). So the positive values of both ΔH° and ΔS° suggest an endothermic reaction and increase in randomness at the solid–liquid interface during the adsorption. ΔG° values obtained were negative indicating a spontaneous adsorption process. The kinetic process was described by a pseudo-second-order rate equation very well. The results of the present study indicated that the QCMS could be considered as a potential adsorbent for Cr (VI) in aqueous solutions.