Removal and recovery of phosphate and fluoride from water with reusable mesoporous Fe3O4@mSiO2@mLDH composites as sorbents

Abstract

Three core/shell/shell MgAl-LDH composites using Fe3O4 microspheres as the core, a SiO2 matrix as the inner layer and a MgAl-LDH layer as the outer shell have been synthesized for the removal and recovery of phosphate and fluoride from water by a magnetic separation technique. The synthetic mesoporous MgAl-LDH composites show good magnetic separability, well-defined pore distributions, and have specific surface areas of 73 m2 g−1, 168 m2 g−1, and 137 m2 g−1 for Fe3O4@SiO2@LDH350, Fe3O4@SiO2@mLDH350, and Fe3O4@mSiO2@mLDH350, respectively. The adsorption isotherms of both phosphate and fluoride on these MgAl-LDH composites can be well fitted with the Langmuir model. The maximum adsorption capacities of 57.07 mg g−1 and 28.51 mg g−1 were obtained on Fe3O4@mSiO2@mLDH350 for phosphate and fluoride, respectively, much higher than those of other LDH-type materials. The adsorbed phosphate and fluoride could be successfully recovered by NaNO3-NaOH solution, and the regenerated MgAl-LDH composites could be reused for phosphate and fluoride removal. Owing to their high adsorption capacities of both phosphate and fluoride, easy magnetic separation from solution, and good reusability, the mesoporous MgAl-LDH composites are expected to have potential applications in removal or recovery of fluoride or phosphate from water.