Abstract

Hyperspectral imaging has recently emerged in the geosciences as a technology that provides rapid, accurate, and high-resolution information from lake sediment cores. Here we introduce a new methodology to infer particle size distribution, an insightful proxy that tracks past changes in aquatic ecosystems and their catchments, from laboratory hyperspectral images of lake sediment cores. The proposed methodology includes data preparation, spectral preprocessing and transformation, variable selection, and model fitting. We evaluated random forest regression and other commonly used statistical methods to find the best model for particle size determination. We tested the performance of combinations of spectral transformation techniques, including absorbance, continuum removal, and first and second derivatives of the reflectance and absorbance, along with different regression models including partial least squares, multiple linear regression, principal component regression, and support vector regression, and evaluated the resulting root mean square error (RMSE), R-squared, and mean relative error (MRE). Our results show that a random forest regression model built on spectra absorbance significantly outperforms all other models. The new workflow demonstrated herein represents a much-improved method for generating inferences from hyperspectral imagery, which opens many new opportunities for advancing the study of sediment archives.

Highlights

  • Hyperspectral imaging has gained attention in the geoscience community because of its detailed representation of sediment features [1]

  • We evaluated several approaches for inferring mean particle size (MPS), including support vector regression (SVR), partial least squares regression (PLSR), multiple linear regression (MLR), principal component regression (PCR), and random forest (RF) regression

  • EvaluaTthioenhoigf hthRe2PvraelduiecstitvheatMreosduelltsed from applying RF models to sediment core reconstructions show

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Summary

Introduction

Hyperspectral imaging (imaging spectroscopy) has gained attention in the geoscience community because of its detailed representation of sediment features [1]. This technique can be used to determine the composition of sediment cores based on the analysis of absorptions at specific wavelengths of electromagnetic radiation [2]. Hyperspectral imaging has shown great promise for the analysis of sediment cores with numerous possible applications [1,4,5], given that it is fast and non-destructive, and represents a high spatial resolution technique (i.e., submillimeter resolution). Corruption of the measured pixels by matrix effects (e.g., water content and porosity) may at times interfere with the interpretation of results [4]

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