Abstract

The manipulation of droplets is used in a wide range of applications, from lab-on-a-chip devices to bioinspired functional surfaces. Although a variety of droplet manipulation techniques have been proposed, active, fast and reversible manipulation of pure discrete droplets remains elusive due to the technical limitations of previous techniques. Here, we describe a novel technique that enables active, fast, precise and reversible control over the position and motion of a pure discrete droplet with only a permanent magnet by utilizing a magnetically responsive flexible film possessing actuating hierarchical pillars on the surface. This magnetically responsive surface shows reliable actuating capabilities with immediate field responses and maximum tilting angles of ~90°. Furthermore, the magnetic responsive film exhibits superhydrophobicity regardless of tilting angles of the actuating pillars. Using this magnetically responsive film, we demonstrate active and reversible manipulation of droplets with a remote magnetic force.

Highlights

  • The manipulation of droplets is used in a wide range of applications, from lab-on-a-chip devices to bioinspired functional surfaces

  • The coating of carbon nanoparticles (CNPs) over the arrays resulted in magnetically actuating hierarchical pillar arrays with superhydrophobicity

  • This is because the CNP coating creates nanoscale roughness over the surface of the micropillars, resulting in micro- and nanoscale combined hierarchical structures. These hierarchical architectures enable the array to maintain reduced contact with the droplet and a superhydrophobic wetting state regardless of the bending angle of the pillar arrays. These results indicate that a discrete droplet would not wet these self-assembled hierarchical pillar arrays even when the arrays are actuating under a magnetic force, which may enable active and reversible manipulation of a droplet on the pillar arrays

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Summary

Introduction

The manipulation of droplets is used in a wide range of applications, from lab-on-a-chip devices to bioinspired functional surfaces. We describe a novel technique that enables active, fast, precise and reversible control over the position and motion of a pure discrete droplet with only a permanent magnet by utilizing a magnetically responsive flexible film possessing actuating hierarchical pillars on the surface. This magnetically responsive surface shows reliable actuating capabilities with immediate field responses and maximum tilting angles of ~90°. We report a novel technique that enables active and dynamic control over the position and motion of a pure discrete droplet by utilizing a magnetically responsive flexible film comprising reversibly actuating hierarchical pillars on the surface. Using this novel magnetically responsive film with a superhydrophobic nature, we demonstrate highly precise and dynamic manipulation of a discrete droplet in an active and instant manner using only a permanent magnet

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