Abstract
Novel strategies for the stereoselective synthesis of molecules with remote stereogenic centers across double bonds have been developed via organoiron methodology allowing highly diastereoselective syntheses of 1,8- and 1,10-diol Fe(CO)3 complexes using the stereospecific 1,3- and 1,5-migration of an Fe(CO)3 group; this strategy could be used for stereoselective functionalization of remote terminal substituents on acyclic polyene compounds.
Published Version
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