Abstract
Cycloaddition of TCNE to 2-methyl-1′,1′,1′-d 3-5-methyl-2,4-hexadiene-1,1,1-d 3 (DMHD-d 6) shows a substantial secondary isotope effect, which depends on solvent polarity. This remote ε- secondary isotope effect is a result of hyperconjugation in the dipolar intermediate which is formed in the rate determining step.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
