Abstract
We prepared crosslinked azobenzene main-chain liquid-crystalline polymers (MCLCPs), in which the exchange of crosslinks can be brought about by transesterification reactions. The exchangeable crosslinks enable reshaping and self-healing of the MCLCPs upon heating. Furthermore, the stress generated by stretching the MCLCP film is completely relaxed at 180 °C through rearrangement of networks. The film after hot-drawing shows reversible bending behavior upon irradiation with UV and visible light.
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Schedule a callMore From: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
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