Remediation of zinc-contaminated soils by using the two-step washing with citric acid and water-soluble chitosan

Abstract

Remediation of heavy metal contaminated soil with appropriate washing agents is crucial to the decline in the harmfulness of contaminated soil by heavy metals to the environment and human health. In this study, citric acid (CA) and water-soluble chitosan (WSCS) as natural and degradable washing agents were used to remove Zn in the soil by two-step washing method. Results indicated that the two-step washing with CA and WSCS were found to be suitable for the removal of Zn from the contaminated soils, which significantly decreased the total concentration of Zn in the soil. After the remediation process with two-step soil washing, the contents of Zn in different chemical species decreased, especially for the carbonate-bound fraction. Therefore, the two-step soil washing with CA and WSCS was advisable for the remediation of Zn-contaminated soils. The washing mechanism could include the acid dissolution, ion exchange and complexation reaction between zinc ions and functional groups such as hydroxyl, carboxyl, amine and amide groups. This study provided the theoretical support for the exploitation and application of suitable washing agents used for the remediation of contaminated soils by heavy metals.