Remediation of uranium-contaminated acidic red soil by rice husk biochar.

Abstract

Uranium (U) in the U-contaminated acidic red soil exhibits high mobility. In the present study, rice husk was used to produce biochar to remediate U-contaminated red soil under acid precipitation. Firstly, batch adsorption experiments showed that the dissolution of alkaline substance in biochar could buffer the pH value of acidic solution. The equilibrium pH value had a crucial influence on biochar adsorption capacity of U, and the neutral equilibrium pH value was favorable for adsorption. Then, the incubation experiments of red soil with biochar were performed, and the Synthetic Precipitation Leaching Procedure (SPLP) extraction of amended red soil showed that the short-term leachability of U was decreased from 26.53% in control group (without biochar) to 1.40% in 10% biochar-amended red soil. Subsequently, the sequential extraction showed that the fraction of U was mainly transformed from exchangeable and Fe/Mn oxide fraction to carbonate fraction after biochar amendment, and the total amount of exchangeable U and carbonate fraction U in soil was increased slightly. Finally, simulated acid rain leaching experiments showed that the capability of amended red soil to resist acid rain acidification was enhanced. And the long-term leachability of U in amended red soil was decreased from 26.37% in control group to 3.18% in the 10% biochar-amended red soil under the simulated acid rain leaching conditions. In conclusion, biochar has passivation effect on U in U-contaminated red soil, which can reduce the long-term and short-term mobility of U in acidic environments. This study provided an experimental basis for the application of biochar in remediation and improvement of U-contaminated acidic red soil.