Remediation of Cr(VI)-contaminated soil by sulfidated zero-valent iron: The effect of citric acid as eluant and modifying agent

Abstract

Leaching and chemical reduction are two commonly used methods for Cr(VI)-contaminated soil remediation. Leaching focuses more on leaching Cr(VI) out of the soil. Chemical reduction has the disadvantages of poor fluidity of reductant. Combining these two remediation methods, this study investigated the performance of Cr(VI)-contaminated soil when H2O and citric acid were used as eluant separately and sulfidated zero-valent iron (SZVI) as reductant. And based on the properties of Cr(VI) chelated with –COOH to form a complex and the characteristics of –OH anchored to FeSx, citric acid modified SZVI (Cit-SZVI) was prepared. The prepared Cit-SZVI was characterized by SEM-EDS, XPS, XRD to study its surface properties. The transformation of Cr species in soil was explored by BCR sequential extraction. The results indicated Cr(VI) removal by SZVI was significantly promoted when citric acid as eluant compared with H2O. With SZVI dosage of 2.0 wt%, 23.1 mg/L Cr(VI) was basically removed within 60 min when citric acid as eluant, while only 60% Cr(VI) was removed when H2O as eluant even after 3 h. The kobs of Cit-SZVI was 1.4 times that of SZVI when H2O as eluant. The characterization of Cit-SZVI showed that more FeSx was formed on the surface of the Cit-SZVI, and more –OH of citric acid was anchored to FeSx, leaving –COOH available to chelate Cr(VI). Compared with H2O as eluant and SZVI/Cit-SZVI as reducing agent, the removal effect of Cr(VI) was the best when citric acid as eluant and SZVI as reducing agent. BCR sequential extraction showed that Cr(VI) was effectually fixed, weak acid extractable Cr proportion decreased significantly and residual Cr proportion increased in the treated soil. The combination of leaching and chemical reduction proposed in this study can greatly enhance the Cr(VI) removal effect in soil, which is important for the remediation of Cr(VI)-contaminated soil.