Remediation of arsenic-contaminated paddy soil by iron oxyhydroxide and iron oxyhydroxide sulfate-modified coal gangue under flooded condition

Abstract

Flooded condition enhances arsenic (As) mobility in paddy soils, posing an imminent threat to food safety and human health. Hence, iron oxyhydroxide and iron oxyhydroxide sulfate-modified coal gangue (CG-FeOH and CG-FeOS) were synthesized for remediation of As-contaminated paddy soils under a flooded condition. Compared to the control, CG-FeOH and CG-FeOS application decreased the soil pH by 0.10–0.80 and 0.13–1.63 units, respectively. CG-FeOH and CG-FeOS application significantly (P < 0.05) decreased available As concentration by 13.46–43.44% and 21.31–54.37%, respectively. CG-FeOH and CG-FeOS significantly (P < 0.05) reduced the non-specifically adsorbed and specifically adsorbed As fractions and increased As(V) proportion by 22.61–26.53% and 29.10–36.51%, respectively. Our results showed that CG-FeOH and CG-FeOS could change As geochemical fraction and valence state, consequently reducing available As concentration in paddy soils. Moreover, the sulfate could enhance the oxidation and co-precipitation of As with CG-FeOH. Compared to CG-FeOH, CG-FeOS was more effective in decreasing available As concentration and oxidizing As(III) to As(V). This study revealed that CG-FeOS is a potential amendment for As immobilization in paddy soils.