Abstract

Abstract Many fundamental problems regarding the mathematical description of non-isothermal reaction kinetics are still the subject of various considerations. In this communication an attempt is made to clarify some aspects concerned with: (1) the use of the degree of conversion in the rate equations; (2) fundamental relationships describing non-isothermal reaction kinetics; (3) the existence of the total differential of α = f( t , T ); (4) the physical meaning of Doyle's assumption; (5) the possibility of the application of non-isothermal techniques on various temperature programs to the investigation of reaction kinetics; and (6) other problems arising on examination of thermodynamics and non-isothermal kinetics of simple thermal processes.

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