Abstract
Abstract The Pseudomonas cepacia lipase-catalyzed trans-esterification of 5-phenyl-1-penten-3-ol was drastically accelerated by 5 mol% of a thiacrown ether additive. The reaction profile was strongly dependent on the nature of the vinyl esters as the acyl donor; the highest acceleration rate was recorded with vinyl chloroacetate, while the highest enantioselectivity was obtained using vinyl acetate.
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