Abstract

This research investigated the use of two relatively cost-effective devices for determining NH3 concentrations in naturally ventilated (NV) dairy barns including an Ogawa passive sampler (Ogawa) and a passive flux sampler (PFS). These samplers were deployed adjacent to sampling ports of a photoacoustic infrared multigas spectroscope (INNOVA), in a NV dairy barn. A 3-day deployment period was deemed suitable for both passive samplers. The correlations between concentrations determined with the passive samplers and the INNOVA were statistically significant (r = 0.93 for Ogawa and 0.88 for PFS). Compared with reference measurements, Ogawa overestimated NH3 concentrations in the barn by ∼14%, while PFS underestimated NH3 concentrations by ∼41%. Barn NH3 emission factors per animal unit (20.6–21.2 g d−1 AU−1) based on the two passive samplers, after calibration, were similar to those obtained with the reference method and were within the range of values reported in literature.

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