Releasing mechanism of ammonium during clayey sediments compaction and its impact on groundwater environment

Abstract

Compaction of clayey aquitard would release pore water containing high levels of ammonium to adjacent aquifers, potentially affecting the concentration of groundwater ammonium. However, the releasing process and impact effect of ammonium within clayey aquitard during compaction remain unknown. Four groups of pre-experiments and two groups of simulation experiments were conducted to reveal the releasing mechanism of ammonium during clayey sediment compaction. (1) The results of Experiment A simulating continuous sedimentation conditions showed that the sediment ammonium transferred into pore water sequentially through desorption of ion exchange form, degradation of organic matter, and simultaneous release of mineral-bound ammonium. The concentration of pore water ammonium was 3.54–8.20 mg N/L, with a significant periodical variation due to sediment ammonium transformation. The lower moisture content (<42.4 %) in the later stage of compaction inhibited the biological transformation of ammonium, and the change in mineral structure caused the isomorphic replacement of K to capture ammonium, resulting in a decrease in ammonium concentration in released pore water. (2) The results of Experiment B simulating artificial compaction conditions (such as land subsidence) showed that the pore water ammonium was primarily caused by desorption of ion exchange form ammonium due to changes in pore structure and moisture content. The ammonium concentration in pore water was 4.72–9.91 mg N/L, with a significant increase in response to a large change in pressure in the short term. (3) The estimate results in the Chen Lake wetland suggested that the contribution of clayey aquitard compaction to groundwater ammonium concentration in the adjacent aquifer would be 2.68–4.29 mg N/L, which accounted for a considerable portion of groundwater ammonium concentration and was far higher than that of advection and diffusion. The findings of this study reveal the releasing mechanism of ammonium during clayey sediments compaction, in which reaction products may affect adjacent aquifers.