Abstract
A new theoretical approach to the description of spectral parameters pionic atoms in the excited states with precise accounting relativistic, radiation and nuclear effects is applied to the study of energy and spectral parameters of transitions between hyperfine structure components. As an example of the present approach presents new data on the energies of the hyperfine structure transitions 5g4f, 5f-4d in the spectrum of pionic nitrogen are presented and it is performed comparison with the corresponding theoretical data by Trassinelli-Indelicato
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