Abstract

We present bound state solutions of the Dirac equation with the improved Rosen-Morse potential energy model. In the non-relativistic limit, the relativistic energy equation becomes the non-relativistic rotation-vibrational energy expression of the diatomic molecule. We find that the relativistic effect of the relative motion of the ions produces an obvious decrease in the vibrational energies for the 33Σg + state of the Cs2 molecule. It is observed that the behavior of the relativistic rotation-vibrational energies in larger rotational quantum numbers remains similar to that of the system with zero rotational quantum number.

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