Abstract

Transition rates, oscillator strengths and line strengths are calculated for electric-dipole (E1) transitions between odd-parity 3s23p63d94l1, 3s23p53d104l2 and 3s3p63d104l1 states and even-parity 3s23p63d94l2, 3s23p53d104l1 and 3s3p63d104l2 (with 4l1 = 4p, 4f and 4l2 = 4s, 4d) in Ni-like ions with the nuclear charges ranging from Z = 34 to 100. Relativistic many-body perturbation theory (RMBPT), including the Breit interaction, is used to evaluate retarded E1 matrix elements in length and velocity forms. The calculations start from a 1s22s22p63s23p63d10 Dirac–Fock potential. First-order RMBPT is used to obtain intermediate coupling coefficients and second-order RMBPT is used to calculate transition matrix elements. Contributions from negative-energy states are included in the second-order E1 matrix elements to ensure the gauge independence of transition amplitudes. Transition energies used in the calculation of oscillator strengths and transition rates are from second-order RMBPT. Lifetimes of the 3s23p63d94d levels are given for Z = 34–100. These atomic data are important in modelling of M-shell radiation spectra of heavy ions generated in electron beam ion trap experiments and in M-shell diagnostics of plasmas.

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