Abstract
Relativistic many-body perturbation theory, including the Breit interaction, is used to evaluate energy levels, radiative matrix elements and autoionization rates for 1s2l2l′ states of lithium-like Mo39 +, Pr56 +, W71 + and Hg77 +. Radiative and non-radiative data are combined to obtain branching ratios, intensities and effective emission rate coefficients of dielectronic satellite lines. Relative intensity factors are shown graphically for the 1s2l′2l″–1s22l radiative transitions in lithium-like ions with nuclear charges Z ranging from 6 to 100; however, our emphasis here is on dielectronic recombination rates in the four lithium-like ions listed above. Such data, for high-Z ions in particular, are relevant to spectroscopic diagnostics of very high-temperature plasmas including future experiments at the International Thermonuclear Experimental Reactor.
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