Abstract

Relative rate constants for the reaction of oxygen atoms with the fluorinated ethylenes in the gas phase have been measured at 23°C with the following results (relative to ethylene): CH2CHF–0.38; CH2CF2–0.22; cis-CHFCHF–0.32; trans-CHFCHF–0.54;CHFCF2–0.57; CF2CF2–1.60. The results are compared with data for other atoms and radicals with the same olefins, and briefly discussed in terms of the electronic changes produced in the double bond by fluorine substitution.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.