Relative quantum yield for the production of O-atom and S-atom from the photodissociation of OCS in the vacuum UV

Abstract

The relative efficiencies for two dissociative channels in the vacuum UV photolysis of carbonyl sulphide have been determined using the flash photolysis-resonance fluorescence technique to measure initial yields of atomic oxygen and atomic sulphur. At wavelengths above 105 nm, the dissociation of OCS to form atomic sulphur exceeded that for the formation of atomic oxygen to such an extent that only an upper limit could be placed on the minor process, Φ S >/ 50 Φ O. In addition, the flash photo-excitation of carbonyl sulphide produced a long-lived spontaneous emission in the UV and vacuum UV that might be due to molecular fluorescence from OCS.