Abstract

Relative integrated intensities are measured for ten bands in the vibrational structure of the astrophysically significant A 5π−X 5π system of CrO by the technique of photographic photometry. Vibrational transition probabilities are computed using the revised molecular constants of the electronic states. Using these results, the variation of electronic transition moment with the internuclear separation is found to be R e ( r) = const. × (1−0.398 r) in the range 1.60 A ̊ < r < 1.72 A ̊ . A smoothed array of band strengths is presented.

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