Relationship between physical and mechanical properties of accelerated weathering and outdoor weathering of PVC-coated membrane material under tensile stress

Abstract

To estimate the photo-oxidation aging performance of PVC-coated membrane material in atmospheric conditions under tensile stresses, the relationship between physical and mechanical properties under accelerated weathering test and outdoor weathering test is studied with the same cumulative UV radiation energy. And then, both tensile strength and whiteness index were measured and compared to characterize the property change of membrane material after aging under four different tensile stresses (0%, 5%, 10% and 20% of the breaking strength), respectively. In addition, FTIR spectrometry was applied to characterize the chemical components of the samples under different weathering conditions, and the carbonyl index was extracted. The results show that there were significant differences of tensile strength and carbonyl index between two kinds of aging conditions, whereas with the increasing tensile stresses, the whiteness index represented a consistent increasing deviation of accelerated weathering from the outdoor weathering. However, the relationship have been built between both whiteness index and tensile strength retention of accelerated weathering and those of outdoor weathering conditions after a Schwarzschild’s modification. Therefore, the service lifespan of PVC-coated membrane materials can be evaluated by accelerated weathering tests under tensile stresses.