Abstract
We studied the relationship between crystal structure and superconductivity in iron-based superconductors. The superconducting phase diagram of LnFeAsO1−y (Ln = rare-earth) is established as a function of the oxygen deficient content which is determined by Rietveld refinement. The relationship between Tc and the Fe–(Pn,Ch)–Fe bond angle (Pn = pnictogen, Ch = chalcogen) indicates that Tc attains a maximum value when Fe(Pn,Ch)4-tetrahedrons form a regular shape. A higher Tc value could be attained with samples containing regular Fe(Pn,Ch)-tetrahedrons, an Fe–(Pn,Ch) bond length that is longer than the Fe–As bond, and an intermediate (Fe plane)–(Fe plane) distance of 9 Å–15 Å.
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