Abstract

The sensitivity of partial oxidation reactions to the structure of the metallic oxides has been recently demonstrated. It follows that surface atomic arrangements will strongly influence the catalytic properties. Consequently, the conditions of preparations and/or activation of a catalyst, the synergy effects observed in complex oxides, and the role of a support have all to be reconsidered with new eyes. Emphasis is therefore placed on structure sensitivity for oxide catalysts although other concepts still hold true.

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