Abstract
Abstract The accumulation of acid-volatile sulfides and its relation with other trace metal-binding sediment constituents may be important mechanisms to determine the suitability of anaerobic sediments to trap trace metals. An investigation into the relationships among acid-volatile sulfides, total organic carbon, and reactive (hydrogen chloride–soluble) iron, manganese, and trace metals of environmental concern (cadmium, copper, nickel, lead, and zinc) was conduced in anaerobic sediments from a disturbed mangrove ecosystem in Sepetiba Bay (SE Brazil). The two main metal contaminants in the study area (cadmium and zinc) presented levels above regional backgrounds (showing enrichment factors up to 8.5 and 9.1, respectively) and a significant correlation, suggesting a contamination source similarity. Positive correlations among total organic carbon, acid-volatile sulfides, and iron and negative correlations of manganese with total organic carbon and acid-volatile sulfides occurred, probably because of (1) o...
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