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Abstract
The direct synthesis of activated strontium and barium with iodobenzene in THF yields the corresponding THF complexes of phenylstrontium and phenylbarium iodide, respectively, which dismutate into the homoleptic compounds MPh 2 and MI 2. Already at low temperatures ether cleavage reactions take place and from this reaction, the oxygen-centered cage [((thf) 2BaPh 2) 4 · (thf)BaO] was isolated and its molecular structure determined.
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