Reinforcing polyamide 1212 nanocomposites with aligned carbon nanofibers

Abstract

In this study, the mechanical properties and structure orientation of pure polyamide 1212 (PA1212) were compared with those of PA1212–carbon nanofibers (CNFs) nanocomposites. The tensile strength of the composite containing 0.3wt.% modified CNFs was improved from 328MPa (pure PA1212) to 373MPa after drawing. The reinforcing effect was investigated in terms of crystallization behavior, crystal morphology, alignment of CNFs, and crystal orientation degree. Spherulites developed into oriented crystals after drawing, and the CNFs aligned along the drawing direction. The heterogeneous nucleation effect of the aligned CNFs improved the crystal orientation degree, which produced the reinforcing effect. The oriented fibril structures with rigid nanofibers acting as nuclei reinforced the entire oriented crystals in the composites.