Regulating steric hindrance in difunctionalized porous aromatic frameworks for the selective separation of Pb(II)

Abstract

Efficient and selective removal of Pb(II) from wastewater with complex matrix remains a challenging task. Porous aromatic frameworks (PAFs) with predesigned functional building blocks provide a favorable platform for the selective separation of Pb(II). Herein, the bifunctional SPAFs with the introduction of -OH and -SO3H were synthesized through rationally optimizing their steric hindrance. As a result, the SPAF-0.75 exhibits favorable adsorption capacity of Pb(II) (212.34mg g-1), which is 22 times larger than pristine framework. Competition experiment indicates that SPAF-0.75 possess the selective removal of Pb(II) without interfering from co-existing metal ions. The removal rate of SPAF-0.75 still retain at 100% after six successive cycles. The DFT calculation illustrates that -OH and -SO3H are co-participate in the process of capturing Pb(II), revealing SPAF-0.75 preferred removal of Pb(II) owing to the lowest adsorption energy (ΔEab= -3.99 eV). This study extend the understanding of the structure-property relationship and facilitate new possibilities for PAFs.