Regularities of formation of adhesive contact “sol-silicate paint - substrate”

Abstract

Introduction. The use as a binder in the manufacture of silicate paints polysilicate solutions obtained by mixing liquid glass and silica sol is considered. To regulate the rheological properties of the paint, improve the filling and prevent the pigment part from sagging, it has been proposed to introduce glycerin into the binder composition. The results of studying the interfacial interaction between the paint and the substrate are given. Materials and methods. In developing the formulation of silicate paints based on polysilicate solutions, MK-2 microcalcite, marshalite, diatomite and talc of MT-GSM grade were used as a filler, and titanium dioxide as a pigment. Polysilicate solutions were obtained by reacting stabilized solutions of colloidal silica (sols) with aqueous solutions of alkali silicates (liquid glasses). Nanosil 20 and Nanosil 30 silicic acid sol were used, produced by the Promsteklocentr PC. Used potassium liquid glass with module M = 3.29. A thermodynamic method was used to assess the interfacial interaction. Results. Shown that the introduction of glycerol into the formulation of a sol of silicate paint promotes a decrease in the interfacial surface tension and a better wetting of the surface of the mortar substrate. An increase in wetting coefficient is observed. Coatings based on sol silicate paints with the addition of glycerin are characterized by increased crack resistance. An increase in tensile strength, maximum tensile properties, and decrease in the elastic modulus of paint membranes based on the composition with glycerol has been established. The values of the free surface energy of the coating based on the sol of silicate paint and the ratio of the polar to the dispersion component of the free energy of the surface are given. Coatings based on sol of silicate paint with the addition of glycerin are characterized by a large value of the free energy of the surface. In the process of moistening a decrease in the free surface energy is observed due to a decrease in the dispersion component. Conclusions. Studies have shown that the introduction of an additive of glycerin in the formulation of a silicate paint sol contributes to an increase in the performance properties of coatings based on it.