Abstract
AbstractAnionic annulation of appropriate 2,3‐disubstituted pyrroles with Michael acceptors provides an expedient route to densely substituted 7‐hydroxyindoles. Intrinsic to the methodology, the resulting substituents are disposed in a fully regiocontrolled manner. The methodology is applicable to the synthesis of 7‐hydroxybenzofurans. None of the indoles/benzofurans or pyrrole synthons synthesized in this study have hitherto been reported.
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